Intermediates and Products of the Hexachlorodisilane Cleavage of Group 14 Element Phosphanes and Amines – Molecular Structure of Di-tert-butyl(trichlorosilyl)phosphane in the Gas Phase Determined by Electron Diffraction andab Initio Calculations

1999 ◽  
Vol 1999 (8) ◽  
pp. 1381-1392 ◽  
Author(s):  
Wolf-W. du Mont ◽  
Lars Müller ◽  
Reiner Martens ◽  
Paul M. Papathomas ◽  
Bruce A. Smart ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Electron Diffraction ◽  
Gas Phase ◽  
Group 14 ◽  
Tert Butyl

scholarly journals Gas Electron Diffraction Then and Now: from trisilyl phosphine to iso-propyl(tert-butyl)(trichlorosilyl)phosphine

2021 ◽  
Author(s):  
David W H Rankin ◽  
Sarah Louise Masters ◽  
Isabella Wagner
Keyword(s):  
Molecular Structure ◽  
Electron Diffraction ◽  
Gas Phase ◽  
Computational Methods ◽  
Gas Electron Diffraction ◽  
Tert Butyl

The gas-phase molecular structure of iso-propyl(tert-butyl)(trichlorosilyl)phosphine has been determined using a combination of gas electron diffraction and computational methods. The structure presents a conformational challenge that required use of the...

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